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The synthesis of glucosinolates deuterium labelled in the glucose fragment

✍ Scribed by Avril A. B. Robertson; Nigel P. Botting

Publisher: John Wiley and Sons
Year: 2006
Tongue: French
Weight: 157 KB
Volume: 49
Category: Article
ISSN: 0022-2135
DOI: 10.1002/jlcr.1141

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✦ Synopsis

A facile synthesis is described for 2,3,4,6-tetra-O-acetyl-thio-b-d-[1-2 H,6-2 H 2 ]glucopyranose, which has been used to make an isotopically labelled desulphoglucosinolate, [1 0 -2 H,6 0 -2 H 2 ]desulfogluconasturtiin. This isotopically labelled building block can be employed to make any glucosinolate or desulfoglucosinolate for use as internal standards for MS based analytical methods.

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