THE SYNTHESIS OF D-GULOSAMINE
✍ Scribed by Tarasiejska, Zofia; Jeanloz, Roger W.
- Book ID
- 126140217
- Publisher
- American Chemical Society
- Year
- 1957
- Tongue
- English
- Weight
- 264 KB
- Volume
- 79
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Aus D‐Xylose entstehen mit Anilin oder __p__‐Toluidin und Blausäure 80–88% stark linksdrehendes __N__‐Aryl‐D‐idosaminsäure‐nitril und 8–12% stark rechtsdrehendes __N__‐Aryl‐D‐gulosaminsäure‐nitril. Das bei katalytischer Hydrierung entstehende D‐Idosamin‐hydrochlorid kristallisierte nich
1,6-Anhydro-b-L-hexopyranoses as valuable building blocks toward the synthesis of L-gulosamine and L-altrose derivatives via the regioselective triflation and benzoylation of 1,6-anhydro-b-L-idopyranose followed by S N 2 substitution with various nucleophiles as key steps is described here.