𝔖 Bobbio Scriptorium
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The synthesis of D-arabinose-5-phosphate

✍ Scribed by Wesley A. Volk


Book ID
115788890
Publisher
Elsevier Science
Year
1960
Weight
199 KB
Volume
37
Category
Article
ISSN
0006-3002

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5-Thio-L-fucopyranose tetraacetate was synthesized in 11 steps from 5-O-trityl-D-arabinofuranose or D-arabinose diethyl dithioacetal by one-carbon elongation at C-5. Highly diastereoselective addition of MeLi in ether to a 1,2-O-isopropylidene-[J-D-arabino-pentodialdo-l,4-furanose derivative was ach