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The synthesis of cycloöctadecanonaene, a new aromatic system

✍ Scribed by Franz Sondheimer; Reuven Wolovsky


Book ID
104249902
Publisher
Elsevier Science
Year
1959
Tongue
French
Weight
166 KB
Volume
1
Category
Article
ISSN
0040-4039

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✦ Synopsis


TRE synthesis and possible aromatic properties of monocyclic hydrocarbons formally containing alternating single and double bonds (vinylogs of benzene) have often been discussed.1 Nevertheless the only member of this series known up to now besides benzene itself is cyclo&?tatetraene, despite numerous synthetic attempts to prepare other members. We now describe the synthesis of cycloactadecanonaene (II) (for brevity named CON in this communioation), the first cyclic polyene after benzene which might be expected to exhibit aromatic properties since (a) it csn probably take up a planar or near planar configuration and (b) it


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