The Synthesis of Antibiotic Sugars
✍ Scribed by Prof. J. S. Brimacombe
- Publisher
- John Wiley and Sons
- Year
- 1971
- Tongue
- English
- Weight
- 879 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
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A novel strategy for the stereoselective synthesis of E-or Zconfigured γ-alkylidenebutenolides was applied to the preparation of the model compounds 6/7 (E) and 8/9 (Z) of the antibiotics tetrenolin (E) and lissoclinolide (Z), respectively. For introducing the α-substituents of the target molecules
From Sugar Lactones to Stereodefined γ-Alkylidenebutenolides -Synthesis of Analogues of the γ-Alkylidenebutenolide Antibiotics Lissoclinolide and Tetrenolin. -Analogues of the antibiotics tetrenolin (XI) and lissoclinolide (XII) are prepared in order to study the influence of the configuration of t
## Abstract For Abstract see ChemInform Abstract in Full Text.
## Abstract In this feature article we review the synthesis of polymerizable vinyl sugars. Many such syntheses start from isopropylidene‐protected sugars, which still have a free OH‐group. These compounds are then converted to polymerizable monomers by esterification or etherification. Selective re