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The synthesis of alkylmanganese(III) complexes. Crystal structure of MnMe(2-Me2NCH2C6H4)2

โœ Scribed by Jozef L. Latten; Ron S. Dickson; Glen B. Deacon; Bruce O. West; Edward R.T. Tiekink


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
672 KB
Volume
435
Category
Article
ISSN
0022-328X

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2-(Me 2 NCH 2 )C 6 H 4 ]SnCl 3 (1) was prepared via (i) salt elimination reaction between RLi and SnCl 4 (1 : 1 molar ratio), in toluene solution, and (ii) redistribution reaction between [2-(Me 2 NCH 2 )C 6 H 4 ] 4 Sn and SnCl 4 (1 : 3 molar ratio), in the absence of a solvent. Recrystallization fr