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Synthesis and Characterization of Hypervalent Organoantimony(III) Compounds Containing the [2-(Me2NCH2)C6H4]2Sb Fragment

✍ Scribed by Laura M. Opris; Ana Maria Preda; Richard A. Varga; Hans J. Breunig; Cristian Silvestru


Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
288 KB
Volume
2009
Category
Article
ISSN
1434-1948

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2-(Me 2 NCH 2 )C 6 H 4 ]SnCl 3 (1) was prepared via (i) salt elimination reaction between RLi and SnCl 4 (1 : 1 molar ratio), in toluene solution, and (ii) redistribution reaction between [2-(Me 2 NCH 2 )C 6 H 4 ] 4 Sn and SnCl 4 (1 : 3 molar ratio), in the absence of a solvent. Recrystallization fr