Solid-State Structure and Behaviour in Solution of Hypervalent Organotin(IV) Derivatives Containing 2-(Me2NCH2)C6H4 Moieties
β Scribed by Richard A. Varga; Klaus Jurkschat; Cristian Silvestru
- Publisher
- John Wiley and Sons
- Year
- 2008
- Tongue
- English
- Weight
- 476 KB
- Volume
- 2008
- Category
- Article
- ISSN
- 1434-1948
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
2-(Me 2 NCH 2 )C 6 H 4 ]SnCl 3 (1) was prepared via (i) salt elimination reaction between RLi and SnCl 4 (1 : 1 molar ratio), in toluene solution, and (ii) redistribution reaction between [2-(Me 2 NCH 2 )C 6 H 4 ] 4 Sn and SnCl 4 (1 : 3 molar ratio), in the absence of a solvent. Recrystallization fr
The title compound has been synthesised, and characterised by multinuclear magnetic resonance spectroscopy, both in solution and in the solid state. The bandshapes of variabletemperature solution-state 19 F NMR spectra have been iteratively fitted to obtain information on the kinetics of rotation ab