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The synthesis of a linear tröger's base derived from naphthalene: 7H-15H-6,14-methanodinaphtho[2,3-b:2′,3′-f][1,5]diazocine

✍ Scribed by Carmen Pardo; Céline Pirat; José Elguero

Publisher
Journal of Heterocyclic Chemistry
Year
2007
Tongue
English
Weight
337 KB
Volume
44
Category
Article
ISSN
0022-152X

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✦ Synopsis

Abstract

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The title compound 3 was prepared in four steps from commercial 3‐amino‐2‐naphthoic acid in an overall 75 % yield. Attempts to use the same approach in the case of 2‐aminonicotinic acid methyl ester failed. All the compounds were characterized by NMR.

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