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The synthesis of 4-(2,6,10-trimethyl-1,3,5,9-undecatetraenyl)benzoic acid based on alkoxy alkene-acetal condensation

โœ Scribed by G. V. Kryshtal'; G. M. Zhdankina; E. P. Serebryakov


Book ID
112387259
Publisher
Springer
Year
1993
Tongue
English
Weight
242 KB
Volume
42
Category
Article
ISSN
1573-9171

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Acetal-protected (2,4-dioxocyclohex-1-yl)acetic acid derivatives were prepared by the allylation of dilithiated 1,3-cyclohexane-1,3diones, by the protection of the carbonyl groups and by the oxidation of the alkene. The products were then transformed, by amide formation and subsequent cyclization, i