𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The synthesis of [3-11C]pyruvic acid, a useful synthon, via an enzymatic route

✍ Scribed by Peter Bjurling; Yasuyoshi Watanabe; Bengt Långström

Book ID
103920086
Publisher
Elsevier Science
Year
1988
Weight
352 KB
Volume
39
Category
Article
ISSN
0883-2889

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Synthesis of [3-11C]phenylpyruvic acid a
Synthesis of [3-11C]phenylpyruvic acid and its use in an enzymatic transamination to [3-11C]phenylalanine
✍ Christer Halldin; Bengt Längström 📂 Article 📅 1986 🏛 John Wiley and Sons 🌐 French ⚖ 257 KB

The synthesis of C3-1 lClphenylpyruvic acid, starting with 11C02, is reported. This a-keto acid was prepared via a condensation reaction, using C 1 'Clbenzaldehyde (prepared as described elsewhere), and 2-phenyl-5-oxazolone, using diazabicyclooCtane (DABCO) da a base. The condensation product , [a-l

A synthesis of (−)-deoxypodocarpic acid
A synthesis of (−)-deoxypodocarpic acid methyl ester via an enzymatic enantioselective hydrolysis of the key intermidiate enol ester
✍ Takeshi Sugai; Hideaki Kakeya; Hiromichi Ohta; Mitsuo Morooka; Shigeru Ohba 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 637 KB

1~,4a~,lOa~)-(-)-l-Methoxycarbonyl-1,4a-d~ethyl-l,2,3,4,4a,9,lO, lOa-octahydrophenanthrene (deoxypodocarpic acid methyl ester l), a useful intermediate for the synthesis of various diterpenes, was synthesized from (R)-(+)-6-ethoxycarbonyl-2,6-dimethyl-l-cyclohexenyl acetate 4. The chiral starting ma