The synthesis of 2,2-d2-cyclohexanone and 2,2-d2-cyclopentanone
β Scribed by Joseph Deutsch; Asher Mandelbaum
- Book ID
- 104239210
- Publisher
- Elsevier Science
- Year
- 1969
- Tongue
- French
- Weight
- 97 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
The synthesis of deuterium labelled organic compounds has been of great importance in the investigation of the mechanisms of organic reactions, in n.m.r. studies and in the determination of fragmentation patterns under electron impact. Rather few examplesof partial
π SIMILAR VOLUMES
R e c e i v e d o n F e b r u a r y 1 9 , 1972.
## Abstract A convenient method for the synthesis of cyclopropyl cyanideβ2,2βd~2~ has been elaborated. Reduction of methyl 3βcyanopropionate with lithium borodeuteride followed by reaction of the resulting alcohol with triphenylphosphine and carbon tetrachloride gave 4βchlorobutyronitrileβ4,4βd~2~.