The synthesis and X-ray study of (η6-benzamide)- and (η6-phenylacetamide)tricarbonyl chromium complexes. Structural effects of the substituent
✍ Scribed by M.M. Kubicki; P. Richard; B. Gautheron; M. Viotte; Š. Toma; M. Hudecek; V. Gajda
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 664 KB
- Volume
- 476
- Category
- Article
- ISSN
- 0022-328X
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## Abstract The Cr(CO)~3~‐complexed η6‐phenylpropargylic alcohols 3 react in a displacement rearrangement with thionyl chloride or chlorodiphenylphosphane to give the chloro‐ or phosphoryl allenyl substituted η6‐phenyl complexes 4 and 6, respectively. In the X‐ray crystal structure of the novel org
The electronic effects of the chromium tricarbonyl fragment on the structure of the benzene ring of (η 6 -C 6 H 6 )Cr(CO) 3 is investigated theoretically using ab initio molecular orbital calculations with electron correlation included by using both Møller-Plesset second-order calculations and densi