The synthesis and X-ray crystal structure of molybdenum oxomethoxide [MoO(OMe)4]2
โ Scribed by Vadim G. Kessler; Andrej V. Mironov; Nataliya Ya. Turova; Alexandr I. Yanovsky; Yuri T. Struchkov
- Book ID
- 108428922
- Publisher
- Elsevier Science
- Year
- 1993
- Tongue
- English
- Weight
- 367 KB
- Volume
- 12
- Category
- Article
- ISSN
- 0277-5387
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Electronic structures of Moo2 (4d2) and molybdatc (4d") are calculated by the discrete-variational Xa method employing [hlo20101'F and [hl004]~-clusters. The calculations indicate that the hlo-0 bond is more covalent in the molybdatc than in hloO2. Lcvcl swucturcs for the valence band region arc in
## Synthesis and X-ray Crystal Structure Analysis of C U ~( C H ~C H ~C O O ) \* ( O P P ~~) ~ The complex of [ C U ( C H ~C H C O O ) ~( O P ~~) ] ~ has been synthesized and its X-ray crystal structure determined at room temperature, M = 975.96, tetragonal, space group: I41/a(#88), Dx = 1.39 g/ c