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The synthesis and stereochemistry of syn-2,3-dithiabicyclo[3.2.1]octan-8-ol

โœ Scribed by R. Marshall Wilson; Douglas N. Buchanan; James E. Davis


Publisher
Elsevier Science
Year
1971
Tongue
French
Weight
353 KB
Volume
12
Category
Article
ISSN
0040-4039

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Stereochemistry of the 1,2-Wittig rearra
โœ Stuart L. Schreiber; Mark T. Goulet ๐Ÿ“‚ Article ๐Ÿ“… 1987 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 259 KB

The [1,2] Wittig rearrangement of P-alkoxyalkyl ally1 ethers has been studied and found to provide syn-1,3-diol derivatives in 14-32% yield and with useful levels of diastereoselection. The rearrangement of a-metalated ethers (Wittig rearrangement) has been of interest to investigators since its di