The reaction of allylic esters of dithiocarboxylic acids with tetracyanoethylene affording 3,3,4,4-tetracyano-6,8-dithiabicyclo[3.2.1]octanes
β Scribed by Igor V. Magedov; Sergey Yu. Shapakin; Victor N. Drozd
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- French
- Weight
- 701 KB
- Volume
- 51
- Category
- Article
- ISSN
- 0040-4020
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## Abstract Ethyl 4βoxoalkanoates 1 react at ambient temperature in dry methanol in the presence of molecular sieve 3 Γ in almost quantitative yield with 3βaminopropanol and 2βaminoethanol to form the bicyclic lactams __rac__β2 and __rac__β3, respectively. Surprisingly, the (Β±)β5βalkylβ4βoxaβ1βazab