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The synthesis and stereochemistry of d-threo-3,4-hexodiulose derivatives

✍ Scribed by J'anos Kuszmann; Gábor Medgyes; Gyula Jerkovics

Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
380 KB
Volume
164
Category
Article
ISSN
0008-6215

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✍ Stephen J. Angyal; Donald C. Craig; János Kuszmann 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 534 KB

The crystal structure of D-threo-3,Chexodiulose was determined, and it showed that the crystalline form is the p/3 anomer. In solution, the (~a anomer is preponderant, although all of its hydroxyl groups are cis to each other. In the crystal, the diulose assumes the endo,exo conformation; in the aqu