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The synthesis and reactivity of μ(1,4)-butanediylbis(manganese pentacarbonyl)

✍ Scribed by Selwyn F. Mapolie; John R. Moss; Louise G. Scott

Book ID
103221591
Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
264 KB
Volume
297
Category
Article
ISSN
0022-328X

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The Synthesis and Structure of Pentacarb
The Synthesis and Structure of Pentacarbonyl (5H-dipyrrolo[1,2-c: 2′,1′-e]imidazol-5-yl)manganese
✍ Ulrich Burger; Celia Perret; Gérald Bernardinelli; E. Peter Kündig 📂 Article 📅 1984 🏛 John Wiley and Sons 🌐 German ⚖ 281 KB

## Abstract The dipyrroloimidazolyl ligand is found to bind the pentacarbonylmanganese group to its central ring __via__ a carbon‐metal σ‐bond. This bonding mode differs greatly from that of known imidazole complexes and from the pentahapto mode encountered with the isoelectronic fluorenyl ligand.