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The synthesis and reactions of ReI carboxylic acids. The X-ray structure of fac-Re(CO)3(dppp)CO2D·0.5C6D6

✍ Scribed by Santosh K. Mandal; Douglas M. Ho; Milton Orchin


Publisher
Elsevier Science
Year
1992
Tongue
English
Weight
747 KB
Volume
439
Category
Article
ISSN
0022-328X

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2-Amino-2,3-dideoxy-D-glucitol-3-sulfonic acid (3) and 2-amino-2,6-dideoxy-o-glucitol-6sulfonic acid (4) were prepared by reduction of 2-amino-2,3 (and 2,6)-dideoxy-D-glucopyranose-3 (and 6)-sulfonic acids with sodium borohydride. The crystal structure of 4 monohydrate (C6H15NOTS.H20) is orthorhombi