Carboxylato-Modified New Oxo-Centred Triruthenium Cluster Compounds with CO and Solvent Ligands: The X-ray Structure of [Ru3O(C2H5CO2)6(CO)(THF)2]
β Scribed by Atsushi Inatomi; Masaaki Abe; Yoshio Hisaeda
- Publisher
- John Wiley and Sons
- Year
- 2009
- Tongue
- English
- Weight
- 385 KB
- Volume
- 2009
- Category
- Article
- ISSN
- 1434-1948
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π SIMILAR VOLUMES
The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.
K 2 W 6 Br 14 (I), Rb 2 W 6 Br 14 (II), and Cs 2 W 6 Br 14 (III) were formed by reactions of W 6 Br 12 with the corresponding alkali metal bromides in evacuated silica tubes with a temperature gradient of 925 K/915 K. (I) crystallizes in the cubic space group Pn3 (no. 201), a = 13.808 A Γ , Z = 4, c