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The Synthesis and Electronic Structure of a Novel [Ni‘S4’Fe2(CO)6] Radical Cluster: Implications for the Active Site of the [NiFe] Hydrogenases

✍ Scribed by Qiang Wang; J. Elaine Barclay; Alexander J. Blake; E. Stephen Davies; David J. Evans; Andrew C. Marr; Eric J. L. McInnes; Jonathan McMaster; Claire Wilson; Martin Schröder


Publisher
John Wiley and Sons
Year
2004
Tongue
English
Weight
253 KB
Volume
10
Category
Article
ISSN
0947-6539

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The nickel complex 2 Ni shows reactivity about 10 3 times greater than that of the cobalt analogue 2 Co . The oxidation ability of the M III (m-O) 2 M III core should be affected by the hindered Tp R ligand system, which can stabilize the 2 oxidation state of the metal centers.