The N-Acylated Derivatives of Parent Complex [{(μ-SCH2)2NH}Fe2(CO)6] as Active Site Models of Fe-Only Hydrogenases: Synthesis, Characterization, and Related Properties

Influence of Tertiary Phosphanes on the

Influence of Tertiary Phosphanes on the Coordination Configurations and Electrochemical Properties of Iron Hydrogenase Model Complexes: Crystal Structures of [(μ-S2C3H6)Fe2(CO)6–nLn] (L = PMe2Ph, n = 1, 2; PPh3, P(OEt)3, n = 1)

✍ Ping Li; Mei Wang; Chengjiang He; Guanghua Li; Xiaoyang Liu; Changneng Chen; Bjö 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 167 KB 👁 1 views

## Abstract A series of mono‐ and disubstituted diiron complexes [(μ‐pdt)Fe~2~(CO)~5~L] [pdt = 1,3‐propanedithiolato; L = PMe~3~ (2), PMe~2~Ph (3PPh~3~ (4), P(OEt)~3~ (5)] and [(μ‐pdt)Fe~2~(CO)~4~L~2~] [L = PMe~2~Ph (6), PPh~3~ (7), P(OEt)~3~ (8)] were prepared as Fe‐only hydrogenase‐active‐site mo