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The Synthesis and Crystal Structures of RbC(SiMe3)3 and CsC(SiMe3)3·3.5 C6H6: A One-dimensional Ionic Solid and an Ionic Solid with a Molecular Structure

✍ Scribed by Prof. Colin Eaborn; Dr. Peter B. Hitchcock; Dr. Keith Izod; Dr. J. David Smith


Publisher
John Wiley and Sons
Year
1995
Tongue
English
Weight
267 KB
Volume
34
Category
Article
ISSN
0044-8249

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The reaction of PhN 3 (H)C 6 H 4 N 3 (H)Ph with Hg(NO 3 ) 2 in THF in the presence of triethylamine yields {Hg[PhN 3 C 6 H 4 N 3 (H)Ph](NO 3 )} as a yellow powder that can be recrystallized from THF/acetone. The crystals belong to the monoclinic system, space group P2 1 with the cell dimensions a ϭ