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Structural Evolution from the Solid State to the Molecule for BaI2: Synthesis and Crystal Structures of [BaI2(μ2-OH2)2]3/∞, [BaI2(μ2-OH2)(OC3H6)]2/∞, [BaI2(thf)3]1/∞, and [BaI2(thf)5] · THF

✍ Scribed by Dr. Katharina M. Fromm


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
402 KB
Volume
36
Category
Article
ISSN
0044-8249

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Treating [Cp\*V(l-Cl) 2 ] 3 (Cp\* = C 5 Me 5 ) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoMe 2 ], respectively, with Me 3 SnF afforded the title compounds [Cp\*V(l-F) 2 ] 4 (1) and [(2,6-i-Pr 2 C 6 H 3 N) 2 MoF 2 ] ´THF ( 2). 1 has a tetrameric structure, in which four V atoms can be regarded as being arranged