The synthesis and chemical properties of methyl 2,3,6-trio-O-benzoyl-4-deoxy-4-thiocyano-α-D-glucopyranoside
✍ Scribed by S.D. Géro
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 259 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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As part of a programme involving X-ray crystallographic studies" of cis-and tpuns-fused hexopyranosides, we now report on the crystal structures of methyl 2-~-methyl-~-D-glucop~anoside\* (11, which was obtained by debe~lidenation of methyl 4,~-O-benzyIidene-2-O-methyI-3-O-~-tolylsulfonyl-~-~-glucopy
The title compound (21) was synthesized from cellobiose as a synthon of a heparin-related oligosaccharide. The per-0-benzyl and per-0-benzoyl derivatives of 1 ,6-anhydro-4-0-(6-deoxy-B-D-~~~lo-hex-5-enopyranosyl)-~-~-glucopyranose were treated with a nonsolvated borane to give a 1 :2 mixture of the