The synthesis and characterization of a cationic technetium(V) phenylimido complex. The X-ray crystal structure of [TcCl2(NPh)(PMe2Ph)3](BPh4)
β Scribed by Terrence Nicholson; Alan Davison; Jon A. Zubieta; Qin Chen; Alun G. Jones
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 325 KB
- Volume
- 230
- Category
- Article
- ISSN
- 0020-1693
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Novel tetrameric rhenium(V) complexes have been prepared from [ReNCl 2 (PPh 3 ) 2 ] and [ReN(PMe 2 Ph) (S 2 CNEt) 2 ], respectively. [ReNCl 2 (PPh 3 ) 2 ] reacts with 1.5 equivalents of KS 2 CNEt 2 in methanol to yield the unusual dark red species [{cyclo-ReN} 4 (S 2 CNEt 2 . The crystal structure
Complexes of the type M{Ph 2 P(CH 2 ) n N CHC 6 H 4 -o-OH} 2 (n= 3, 4 and M= cis-and trans-PdCl 2 , cis-PtCl 2 , cis,cis,trans-RuCl 2 (CO) 2 ) have been synthesized by the reactions of the ligands with the appropriate metal precursors. All of the complexes are obtained in high yields, and, in all of