The superposition of small deformations on large deformations: Measurements of the incremental relaxation modulus for a polyisobutylene solution
β Scribed by McKenna, G. B. ;Zapas, L. J.
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1985
- Tongue
- English
- Weight
- 450 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0098-1273
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β¦ Synopsis
Abstract
The incremental relaxation modulus Ξ__G__(t) for a concentrated solution of polyisobutylene has been determined from stepβshear experiments in which a small deformation ΞΞ³ was superimposed on a large deformation Ξ³~1~; Ξ__G__(t) was found to decrease with increasing Ξ³~1~ and to increase with the time t~e~ after the imposition of the large deformation. It was also observed that the βapparent relaxation specturmβ associated with Ξ΄__G__(t) narrows and shifts to shorter times when compared to the spectrum associated with the linear viscoelastic relaxation modulus G(t). The results are well described by the nonlinear constitutive equation of the BKZ elastic fluid theory.
π SIMILAR VOLUMES
For small axially symmetric deformations of isotropic incompressible hyperelastic materials which are superimposed upon the symmetrical expansion of a spherical shell, new closed form solutions are derived without any restrictions on the strain-energy function. These solutions are used to derive the
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