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The superposition of small deformations on large deformations: Measurements of the incremental relaxation modulus for a polyisobutylene solution

✍ Scribed by McKenna, G. B. ;Zapas, L. J.


Publisher
Wiley (John Wiley & Sons)
Year
1985
Tongue
English
Weight
450 KB
Volume
23
Category
Article
ISSN
0098-1273

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✦ Synopsis


Abstract

The incremental relaxation modulus Ξ”__G__(t) for a concentrated solution of polyisobutylene has been determined from step‐shear experiments in which a small deformation Δγ was superimposed on a large deformation Ξ³~1~; Ξ”__G__(t) was found to decrease with increasing Ξ³~1~ and to increase with the time t~e~ after the imposition of the large deformation. It was also observed that the β€œapparent relaxation specturm” associated with Ξ΄__G__(t) narrows and shifts to shorter times when compared to the spectrum associated with the linear viscoelastic relaxation modulus G(t). The results are well described by the nonlinear constitutive equation of the BKZ elastic fluid theory.


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