The sulphur(II)?nitrogen bond. Part I. Reaction of alkanesulphenyl chlorides with secondary amines
โ Scribed by Armitage, D. A.; Clark, M. J.
- Book ID
- 120939401
- Publisher
- The Royal Society of Chemistry
- Year
- 1971
- Tongue
- English
- Weight
- 442 KB
- Volume
- 0
- Category
- Article
- ISSN
- 0022-4952
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
While several substitution meohauisms of 8 leaving group attoohed to a ;CX: bond arelmown,' those at 8 ;c?r-bond were little etudied. The kinetios of the hydrolyeis of the -C(Cl)=lF system was studied only by Ugi\* =d that of the -C(X)\*-lV-system by Soott end ooworkers.3 Intermediate nitrilium hali
Secondary amines and amides react spontaneously with perhalofluoroalkanes CF2BrCFBrX(X = F, Cl, CF3) to afford N-perhalofluoroalkylated tertiary amines in fair to good yields. Evidence for an anionic chain process initiated by the bromophilic attack