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N-Perhalofluoroalkylation of secondary amines by the reactions of the amines and amides with perhalofluoroalkanes. Halophilic attack on nitrogen nucleophile on CBr bond.

✍ Scribed by Xing-ya Li; He-qi Pan; Xi-kui Jiang

Book ID: 104227764
Publisher: Elsevier Science
Year: 1987
Tongue: French
Weight: 231 KB
Volume: 28
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)96359-7

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✦ Synopsis

Secondary amines and amides react spontaneously with perhalofluoroalkanes CF2BrCFBrX(X = F, Cl, CF3) to afford N-perhalofluoroalkylated tertiary amines in fair to good yields. Evidence for an anionic chain process initiated by the bromophilic attack

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