The Sulfonamide-Aminosulfone Rearrangement:A Rearrangement Induced Anionically, Cationically, and Thermally
β Scribed by Prof. Dr. Dieter Hellwinkel; Dipl.-Chem. Martin Supp
- Publisher
- John Wiley and Sons
- Year
- 1974
- Tongue
- English
- Weight
- 123 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0044-8249
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
A 4 K matrix ESR study shows that the molecular radrcal cations of isopropyl formate and acetate, produced radio-IyticaJly in halocarbon matrices at 4-2 I(, undergo spontaneous rearrangement due to a selective intramolecular hydrogen shift from the tertiary C-H bond in the isopropyl group to the car
## Abstract The stepwise and concerted pathways for the McLafferty rearrangement of the radical cations of butanal (Bu^+^) and 3βfluorobutanal (3FβBu^+^) are investigated with density functional theory (DFT) and __ab initio__ methods in conjunction with the 6β311+G(d,p) basis set. A concerted trans