A 4 K matrix ESR study shows that the molecular radrcal cations of isopropyl formate and acetate, produced radio-IyticaJly in halocarbon matrices at 4-2 I(, undergo spontaneous rearrangement due to a selective intramolecular hydrogen shift from the tertiary C-H bond in the isopropyl group to the car
A 4 k matrix esr study of the radical cations of methyl formate: The primary radical cation and its rearrangement
β Scribed by Machio Iwasaki; Hachizo Muto; Kazumi Toriyama; Keichi Nunome
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 372 KB
- Volume
- 105
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The intensity ratio of two Raman bands was measured at various resonant excitation wavelengths for the radical cation of naphthalene. By comparing the observed intensity ratio with calculation, the partitioning of the electronic spectral width into homogeneous and inhomogeneous components was perfor
In contrast to recent claims by Rhodes and Glidewell, comparison of both ESR and electronic absorption spectra shows that the photoproduct of the recently characterized radical cation of bicyclo[ 3.3.0]octa-2,6-diene-4,8-diyl is identical to the 1,4dihydropentalene radical cation, i.e. a linear conj
In contrast with previous studies, it is found that the most stable structure of the GeH: radical cation has C, symmetry and the relative stability decreases in the order C,> Crv> D2.+ In addition no Cgv structure can be a minimum on the potential energy surface of GeH: . The most stable C, structur