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The GeH4+ radical cation. An ab initio study of its ground-state structure and kinetic stability

✍ Scribed by Takako Kudo; Shigeru Nagase

Publisher: Elsevier Science
Year: 1988
Tongue: English
Weight: 478 KB
Volume: 148
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(88)87263-4

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✦ Synopsis

In contrast with previous studies, it is found that the most stable structure of the GeH: radical cation has C, symmetry and the relative stability decreases in the order C,> Crv> D2.+ In addition no Cgv structure can be a minimum on the potential energy surface of GeH: . The most stable C, structure dissociates relatively easily to GcH: t Hz rather than to GeH: + H.

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