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The Submillimeter-Wave Rotational Spectrum of Fluoroform: Analysis of the K = 3 Line Doubling

✍ Scribed by R. Bocquet; D. Boucher; W.D. Chen; D. Papousek; G. Wlodarczak; J. Demaison

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
508 KB
Volume
163
Category
Article
ISSN
0022-2852

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✦ Synopsis

The millimeter- and submillimeter-wave spectra of (\mathrm{CHF}{3}, v=0, v{3}=1,{ }^{13} \mathrm{CHF}{3}, \boldsymbol{v}=\mathbf{0}, \mathrm{CDF}{3}), (v=0, v_{2}=1, v_{3}=1), and ({ }^{13} \mathrm{CDF}{3}, v=0) have been observed and accurate rotational and centrifugal distortion constants have been derived from their analysis. The splitting of the (K=3) lines of (\mathrm{CHF}{3}) and (\mathrm{CDF}{3}) has been observed for high- (J) values and the splitting constant (h{3}) has been determined. The (J) dependence of the (h_{3}) coefficient was also pointed out. Β§ 1994 Academic Press. Inc.

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