The structures of condelphine, isotalatizidine and talatizidine
β Scribed by S.W. Pelletier; L.H. Keith; P.C. Parthasarathy
- Book ID
- 104215706
- Publisher
- Elsevier Science
- Year
- 1966
- Tongue
- French
- Weight
- 238 KB
- Volume
- 7
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
Recent reportslw3 describe the isolation of the alkaloids denudatine and denudatidine from the roots of Delphinium denudatum. We found neither of these compounds in our extraction of these roots* but instead found two different alkaloids: 0.25% of an alkaloid (I) which melted 15B-15pand a small amount of another (II) which melted 116-l 17" and is identical with the saponification product of I. A later comparison of I with an authentic sample of condelphine has shown conclusively that they are the same**.
π SIMILAR VOLUMES
The phenolic alkaloid atheroline was extracted from the bark of Atherosverma moschatum (1) and vas shown to yield the known but unnamed alkaloid I (2) on methylation of its phenolic group. The latter group was tentatively assigned to C, from its pronounced acidity, and from n.m.r. and i.r. evidence