## Conformations of (l-2)-, (l&+3)-, and (l-4)linked disaccharide methyl glycosides involving aldohexopyranose residues have been studied on the basis of the inter-unit n.0.e. and theoretical calculations using atom-atom potential functions. The preferred conformations and the n.0.e. values are de
The structures of bakkenolides-B, -C and -D as determined by the use of a nuclear overhauser effect.
β Scribed by Nobuo Abe; Ryoichi Onoda; Kunikatsu Shirahata; Tadahiro Kato; M.C. Woods; Yoshio Kitahara; Katsuo Ro; Tozaburo Kurihara
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- French
- Weight
- 271 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0040-4039
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β¦ Synopsis
In addition to the previously reported bakkenolide-A, structure 11, and bakkenolide -B, 1,2,3 two new sesquiterpenoids, bakkenolides-C and -D, have been isolated from the bud of Petasites japonicus subsp. giganteus Kitam. The structures of the last three compounds are discussed in this communication 4 . CHCl Bakkenolide-B (II), [m.p. lOl-102",
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