𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The Structure of Tris(diphenylthiophosphinoyl)methanide, a Mesomerically Stabilized Carbanion

✍ Scribed by Professor Samuel O. Grim; Dr. Richard D. Gilardi; Mr. Samuel A. Sangokoya

Book ID
101552417
Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
175 KB
Volume
22
Category
Article
ISSN
0044-8249

No coin nor oath required. For personal study only.

πŸ“œ SIMILAR VOLUMES

Polydentate ligands containing phosphoru
Polydentate ligands containing phosphorus. 8. Coordination complexes of a new uninegative tridentate ligand, tris(diphenylthiophosphinoyl)methanide, and related compounds and the molecular structure of (bis(dimethylthiophosphinoyl)(diphenylthiophosphinoyl)methanido)chloromercury(II)
✍ Grim, Samuel O.; Smith, Patricia H.; Nittolo, Suzanne; Ammon, Herman L.; Satek, πŸ“‚ Article πŸ“… 1985 πŸ› American Chemical Society 🌐 English βš– 895 KB
X-Ray Structure Analysis of the Li2-Comp
X-Ray Structure Analysis of the Li2-Compound of Bis(trimethylsilyl)metnyl Phenyl Sulfone; Structural Units of an Ξ±-Sulfonyl- and a Complex-Stabilized ortho-Sulfonyl-β€œCarbanion”
✍ Dipl.-Chem. Werner Hollstein; Dr. Klaus Harms; Michael Marsch; Prof. Dr. Gernot πŸ“‚ Article πŸ“… 1987 πŸ› John Wiley and Sons 🌐 English βš– 281 KB πŸ‘ 1 views

Thermal as well as photochemical decomposition of 6 in I ,2-dichloroethylene, styrene or fumarates (as solvent) leads exclusively to the dimers 19 and 20, and even with N-phenylmaleimide the dimerization can only be suppressed with excess of the reagent. Since the ratio of trapping products to dimer