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The Structure of Tris(diphenylthiophosphinoyl)methanide, a Mesomerically Stabilized Carbanion

✍ Scribed by Prof. Samuel O. Grim; Dr. Richard D. Gilardi; Samuels A. Sangokoya

Book ID
101552410
Publisher
John Wiley and Sons
Year
1983
Tongue
English
Weight
201 KB
Volume
22
Category
Article
ISSN
0044-8249

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Thermal as well as photochemical decomposition of 6 in I ,2-dichloroethylene, styrene or fumarates (as solvent) leads exclusively to the dimers 19 and 20, and even with N-phenylmaleimide the dimerization can only be suppressed with excess of the reagent. Since the ratio of trapping products to dimer