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The structure of triphenyl[α-(phenylseleno)phenacylidene]phosphorane

✍ Scribed by Husebye, S. ;Meyers, E. A. ;Zingaro, R. A. ;Braga, A. L. ;Comassetto, J. V. ;Petragnani, N.


Book ID
114503979
Publisher
International Union of Crystallography
Year
1986
Tongue
English
Weight
532 KB
Volume
42
Category
Article
ISSN
0108-2701

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Using a test based on kinetic resolution the aphenylseleno-alkyllithium compounds 3 have been shown to undergo enantiomer equilibration at -105 °C with a rate comparable to that of their addition to aldehydes . At -125 C in Me-THF as solvent, the a-phenylseleno-alkyllithium compounds 10 were found t