Further analysis of the antimicrobial activity of α-phenylseleno citronellal and α-phenylseleno citronellol
✍ Scribed by Francine N. Victoria; Cátia S. Radatz; Maraísa Sachini; Raquel G. Jacob; Diego Alves; Lucielli Savegnago; Gelson Perin; Amanda S. Motta; Wladimir P. Silva; Eder J. Lenardão
- Book ID
- 116486472
- Publisher
- Elsevier Science
- Year
- 2012
- Tongue
- English
- Weight
- 270 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0956-7135
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📜 SIMILAR VOLUMES
The reaction of ~t,~-unsaturated acetals with diisobutylaluminum phenylselenolate followed by treatment with H20 affords the corresponding 1-alkoxy-3-phenylseleno-l-alkenes in good yields. When aq. HCI instead of H20 was employed in the workup, 3-phenylselenoalkanals were formed in good yields.
Trimethyl 3-(phenylseleno)orthopropionate may be utilized as a synthon for the preparation of either 2-substituted acrylates or a-methylene-Y-butyrolactones via Claisen ortho ester rearrangement with allylic alcohols followed by oxidative-elimination of PhSeOH. The 2-substituted acrylate moiety is p