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Selective synthesis of 1-alkoxy-3-phenylseleno-1-alkenes and 3-phenylselenoalkanals by the reaction of diisobutylaluminum phenylselenolate with α,β-unsaturated acetals

✍ Scribed by Yutaka Nishiyama; Tomoyuki Asano; Yoshihiro Kishimoto; Kazuyoshi Itoh; Yasutaka Ishii

Publisher
Elsevier Science
Year
1998
Tongue
French
Weight
130 KB
Volume
39
Category
Article
ISSN
0040-4039

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✦ Synopsis

The reaction of ~t,~-unsaturated acetals with diisobutylaluminum phenylselenolate followed by treatment with H20 affords the corresponding 1-alkoxy-3-phenylseleno-l-alkenes in good yields. When aq. HCI instead of H20 was employed in the workup, 3-phenylselenoalkanals were formed in good yields.

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