Capability of [Re III (tu-S) 6 ]Cl 3 , where tu = thiourea, as a precursor to other Re III complexes by ligand substitution in aqueous medium is studied. For the decomposition of [Re(tu-S) 6 ]Cl 3 , experiments suggest pseudo first order kinetics and observed rate constants vary from 1.3 Β΄10 Β±2 to 9
The structure of thiodithiazyl chlorodisulphate, S3N2S2O6Cl and its preparation from thiodithiazyl monochloride, S3N2Cl
β Scribed by Arthur J. Banister; Howard G. Clarke; Ivan Rayment; Harrison M.M. Shearer
- Publisher
- Elsevier Science
- Year
- 1974
- Weight
- 267 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0020-1650
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π SIMILAR VOLUMES
The barium perfluoroalkanedisulfonates Ba(O 3 S) 2 (CF 2 ) n (n = 1, 3Β±5) and the new potassium fluoroalkanedisulfonates K 2 (O 3 S) 2 CHF, K 2 (O 3 S) 2 CF 2 , and K 2 (O 3 S) 2 (CF 2 ) 5 have been prepared by reaction of (CF 2 ) n (SO 2 F) 2 (n = 1, 3Β±5) or CHF(SO 2 F) 2 with CaO (or Ca(OH) 2 ) an
C and characterized by single-crystal XRD methods. The structure (monoclinic, C2/m, Z = 4) is built-up from five crystallographically distinct Pr 3+ cations which are connected with three kinds of N 3-ions, forming two types of translationally commensurate chains of interconnected [NPr 4 ] tetrahedr