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ChemInform Abstract: Nitride Sulfide Chlorides of the Lanthanides. Part 3. Synthesis and Crystal Structure of Pr5N3S2Cl2.

โœ Scribed by F. LISSNER; T. SCHLEID

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

C and characterized by single-crystal XRD methods. The structure (monoclinic, C2/m, Z = 4) is built-up from five crystallographically distinct Pr 3+ cations which are connected with three kinds of N 3-ions, forming two types of translationally commensurate chains of interconnected [NPr 4 ] tetrahedra. In chain I condensation of two single chains of cis-edge-sharing [NPr 4 ] tetrahedra leads to double chains 1 โˆž[N2Pr3] 3+ while in chains II single chains of vertex-sharing [NPr 4 ] tetrahedra are condensed to the double chains 1 โˆž[NPr2]

3+ . The cationic double chains are linked by S 2-and Cl -anions. -

๐Ÿ“œ SIMILAR VOLUMES

ChemInform Abstract: The Reaction of P3N
ChemInform Abstract: The Reaction of P3N3Cl4(NH2)2 with HCl; Crystal Structure of P3N3Cl5( NH2).
โœ M. ALBERTI; J. BRINEK; J. MAREK; J. TOUZIN ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› John Wiley and Sons โš– 27 KB ๐Ÿ‘ 1 views

The Reaction of P3N3Cl4(NH2)2 with HCl; Crystal Structure of P3N3Cl5( NH2). -The title compound (II) crystallizes in the triclinic space group P1 with Z = 2. (II), as well as (III) (obtained in another solvent) are further characterized by IR and Raman spectroscopy. The IR spectrum of (III) suggest