𝔖 Bobbio Scriptorium
✦   LIBER   ✦

The structure of the cycloaddition products of α-ketonitrilimines to α, β-unsaturated ketones

✍ Scribed by Saleh T. Ezmirly; Ahmad S. Shawali; Ahmad M. Bukhari


Publisher
Elsevier Science
Year
1988
Tongue
French
Weight
486 KB
Volume
44
Category
Article
ISSN
0040-4020

No coin nor oath required. For personal study only.

✦ Synopsis


The cycloaddition of C-ethoxycarbonyl-N-arylnitrilimines 2 and their C-acetyl analogs 4 to a,B-unsaturated ketones 2 give predominantly the 5-acyl-4-aryl-2-pyraxoline derivatives s and 2 respectively.


📜 SIMILAR VOLUMES


Quantitative structure-electrochemistry
✍ P. Tömpe; Gy. Clementis; I. Petneházy; Zs.M. Jászay; L. Tőke 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 661 KB

The half-wave potential (E,,,) of 26 substituted cu,P-unsaturated ketones in non-aqueous acetonitrile were used in Hammett type quantitative structure-activity relationship (QSAR) analysis. A linear relationship between E,,, and the electronic substituent constant, a, and reaction constant pR was re

The Clemmensen Reduction of α, β-Unsatur
✍ Charles W. Jefford; André F. Boschung 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 German ⚖ 525 KB

## Abstract Eleven structurally different α, β‐unsaturated ketones were subjected to the __Clemmensen__ reduction under anhydrous conditions using amalgamated zinc, hydrogen chloride in a solution of ethyl ether, and acetic anhydride. In all cases but one the formation of cyclopropyl acetates was o