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The structure of propadienone (CH2CCO)

✍ Scribed by Leslie Farnell; Leo Radom

Publisher: Elsevier Science
Year: 1982
Tongue: English
Weight: 341 KB
Volume: 91
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(82)83303-4

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✦ Synopsis

A complete ro structure has been obtamcd for propadnmonc (CH,=C=C=O) wlh lhc a1d of 3b uutlo molecularabaal calcuhtlons. The effect of electron correlation has been invcstrgatcd usrng thud-order kllcr-Plcssct pcrturbatlon theory. The molecule is found IO be planar bent (CCC = 145") and the calculated strwturc ylclds rotatlond constants which arc m good agreement wth eupcruncntal values

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