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The structure of nitro-anion-radicals. An investigation employing electron spin resonance spectroscopy and INDO (intermediate neglect of differential overlap) molecular orbital calculations

✍ Scribed by Gilbert, Bruce C.; Trenwith, Michael


Book ID
118273222
Publisher
Royal Society of Chemistry
Year
1973
Tongue
English
Weight
796 KB
Volume
14
Category
Article
ISSN
1472-779X

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## Abstract Radical anions of alkyl α‐oxocarbothioates and α‐oxocarbodithioates are generated by __in situ__ electroreduction. Their spin density distribution and configuration are discussed in terms of the ESR spectra and semi‐empirical (McLachlan‐type and AM1) MO calculations.