✦ LIBER ✦
ESR studies on carboxylic esters. Part 13—electron spin resonance spectroscopy and molecular orbital calculations on the radical anions of 2-oxo-carbothioate and 2-oxo-carbodithioate esters
✍ Scribed by J. Gassmann; H. Günther; K. Osternack; A. Sawluk; K. Thimm; J. Voss
- Publisher
- John Wiley and Sons
- Year
- 1994
- Tongue
- English
- Weight
- 497 KB
- Volume
- 32
- Category
- Article
- ISSN
- 0749-1581
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✦ Synopsis
Abstract
Radical anions of alkyl α‐oxocarbothioates and α‐oxocarbodithioates are generated by in situ electroreduction. Their spin density distribution and configuration are discussed in terms of the ESR spectra and semi‐empirical (McLachlan‐type and AM1) MO calculations.