## Azadirachtin (1) can be converted to the natural product 22,23-dihydro-23Pmethoxyazadirachtin (2) via selective bromomethoxylation of the C-22,23 enol ether double bond and tri-
✦ LIBER ✦
The structure of azadirachtin and 22,23-dihydro-23β-methoxyazadirachtin
✍ Scribed by Wolfgang Kraus; Michael Bokel; Adolf Klenk; Helmut Pöhn
- Book ID
- 104229172
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- French
- Weight
- 274 KB
- Volume
- 26
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
basis of NMR data including NOE experiments, 13C deuterium isotope shifts, and C H long range coupling we suggest structure 1 and 2 for azadirachtin, and 22,23dihydro-23l3+ethoxyazadirachtin, resp.
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