The crystal structure of a triclinic form of the copper(D) complex of Sethoxy-2-oxobutymldehyde bis(thiosemicarbasone) (CuKTS) has been determined\_ The KT8? coordinates to copper(I1) as a tetradentate ligand via two nitrogen and two sulphur atoms. The unit cell is triclinic, space group Pi, with di
The structure of aqua[3-ethoxy-2-oxobutyraldehyde bis(thiosemicarbazonato)]zinc(II)
โ Scribed by Bourne, P. E. ;Taylor, M. R.
- Book ID
- 114527156
- Publisher
- International Union of Crystallography
- Year
- 1980
- Weight
- 324 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0567-7408
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The copper complex, 3-ethoxy-2axobutyraldehyde bis(thiosemicarbazonato) copper( slowly oxidizes thiol groups. Under conditions of excess thiol, the reaction leads to the dissociation of CuKTS\_ On the basis of pH and concentration studies of the rate of reaction, mechanisms are proposed for the reac
The formation constants, reduction potentials. and kinetics of some redox and substitution reactions are reported for a series of bis(thiosemicarbazonato) mpper(II) complexes\_ Linear free energy CorreIations are developed using reduction potentials ss the independent variable in the con-cl&ions-The