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The structure of 2-amino-5,5-dimethyl-1-pyrroline and its N-oxide

✍ Scribed by A.R. Forrester; R.H. Thomson


Publisher
Elsevier Science
Year
1963
Weight
461 KB
Volume
19
Category
Article
ISSN
0371-1951

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A new ring transformation: Synthesis of
✍ Christian Deshayes; Suzanne Gelin πŸ“‚ Article πŸ“… 1981 πŸ› Elsevier Science 🌐 French βš– 358 KB

The nitrosation of some y,&unsaturated B-diketo compounds affords the 3-substituted 4-oxo-5,6-dihydro-1,2,4ff-oxaxines. These compounds are converted to the isomeric 3-oxo-1-pyrroline l-oxides by a facile thermal rearrangement. In connection with our study of y,s-unsaturated 6-ketoesters1'2, we have