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The structure directing effect of organic cations onto the crystal structures of layered thioantimonates(III): Solvothermal synthesis and crystal structures of five new compounds containing the 2∞[Sb8S13]2− anion

✍ Scribed by Angela Puls; Christian Näther; Ragnar Kiebach; Wolfgang Bensch


Book ID
113913136
Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
968 KB
Volume
8
Category
Article
ISSN
1293-2558

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The Structure Directing Effect of Organi
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Solvothermal syntheses, crystal structur
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Five new thioantimonates have been synthesized in the presence of organic amines under solvothermal conditions and their structures determined by single-crystal X-ray diffraction. All of the compounds are layered and contain antimony-sulphide anions of stoichiometry [Sb 4 S 7 ] 2À , but the structur

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The novel thioantimonate(III) [Fe(C 4 H 13 N 3 ) 2 ]Sb 6 S 10 • 0.5 H 2 O was synthesised under mild hydrothermal conditions by allowing elemental Fe, Sb, and S to react in a 50% diethylenetriamine (dien) solution. The compound crystallises in the monoclinic space group C2/c with a = 33.789(3), b =